From: Structural effects on kinetics and a mechanistic investigation of the reaction between DMAD and N–H heterocyclic compound in the presence of triphenylarsine: spectrophotometry approach
∆H‡ kJ mol−1
∆S‡ kJ mol−1K−1
T∆ S‡ kJ mol−1
E aa kJ mol−1
E ba kJ mol−1
A M−1min−1
Arrhenius Eq. 2. and Eyring Eq. 3
17.4 ± 0.5
−175.8 ± 1.7
−51.17
19.9 ± 0.5
19.8 ± 0.5
1.1 × 104