Table 4 List of abbreviations

Nap

Naphthalene

InChI=1/C10H4Cl4/c11-7-5-3-1-2-4-6(5)8(12)10(14)9(7)13/h1-4H

Ace

Acenaphthene

InChI=1/C12H10/c1-3-9-4-2-6-11-8-7-10(5-1)12(9)11/h1-6H,7-8H2

Flo

Fluorene

InChI=1/C13H10/c1-3-7-12-10(5-1)9-11-6-2-4-8-13(11)12/h1-8H,9H2

Phe

Phenanthrene

InChI=1/C14H10/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h1-10H

Ant

Anthracene

InChI=1/C14H10/c1-2-6-12-10-14-8-4-3-7-13(14)9-11(12)5-1/h1-10H

Flu

Fluoranthene

InChI=1/C16H10/c1-2-8-13-12(7-1)14-9-3-5-11-6-4-10-15(13)16(11)14/h1-10H

Pyr

Pyrene

InChI=1/C16H10/c1-3-11-7-9-13-5-2-6-14-10-8-12(4-1)15(11)16(13)14/h1-10H

BaA

Benzo [a]anthracene

InChI=1/C18H12/c1-2-7-15-12-18-16(11-14(15)6-1)10-9-13-5-3-4-8-17(13)18/h1-12H

Chr

Chrysene

InChI=1/C18H12/c1-3-7-15-13(5-1)9-11-18-16-8-4-2-6-14(16)10-12-17(15)18/h1-12H

BkF

Benzo [k]fluoranthene

InChI=1/C20H12/c1-2-6-15-12-19-17-10-4-8-13-7-3-9-16(20(13)17)18(19)11-14(15)5-1/h1-12H

BaP

Benzo [a]pyrene

InChI=1/C20H12/c1-2-7-17-15(4-1)12-16-9-8-13-5-3-6-14-10-11-18(17)20(16)19(13)14/h1-12H

Ind

Indeno [1,2,3-cd]pyrene

InChI=1/C22H12/c1-2-7-17-16(6-1)18-11-10-14-9-8-13-4-3-5-15-12-19(17)22(18)21(14)20(13)15/h1-12H

PAH

Polycyclic Aromatic Hydrocarbon

PDMS

PolyDiMethylSiloxane

MeOH

Methanol

aq

Water

free

Water

p

Polymer

Unit

SPME

Solid Phase Micro-Extraction

ESD

Eqilibrium Sampling Device

A/V

(surface)Area to Volume ratio

m^-1

LoQ

Limit of Quantification

QA/QC

Quality Assurance/Quality Control

PTFE

PolyTetraFluoroEthylene

a

Chemical (thermodynamic) activity

γ_i

Activity coefficient in phase i

M^-1

K _i/j

Partition ratio between phases i and j

L/L

C _i

Concentration in (phase) i

M

T

Thermodynamic temperature

K

T_m

Melting point temperature

K

V_i

Volume of phase i

L

n_a

Amount of analyte

mol

S_(s)i

Solubility (solid) in phase i

M

n

number of replicate determinations

r²

Goodness of fit